06-22U
06-22U
Investigation of the thermodynamic properties of the partially deuterated Rb(H$_{1-x}$D$_x$)$_2$PO$_4$\ ferroelectrics
The research of the physical properties of Rb(H$_{1-x}$D$_x$)$_2$PO$_4$\ crystals was performed in the framework of proton ordering model with tunneling in cluster approximation. The RbD$_2$PO$_4$'s\ model parameters were derived under condition of acceptable description of the experimental data for crystal's thermodynamic characteristics. On the basis of the introduced procedure deriving parameters for Rb(H$_{1-x}$D$_x$)$_2$PO$_4$\ crystals, the thermodynamic properties of these crystals was calculated and the results were compared to the experimental ones. The adequacy of the models with and without tunneling to the description of Rb(H$_{1-x}$D$_x$)$_2$PO$_4$\ crystals was compared. The problem of applying the mean crystal approximation to analysis of physical characteristics Rb(H$_{1-x}$D$_x$)$_2$PO$_4$\ crystals was discussed.