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07-26U

07-26U


By icmp_admin - Posted on 08 February 2012

UDC: 
537.2; 537.3; 537.622; 537.9;
PACS: 
75.10.Hk, 75.10.Nr, 77.22.ch, 77.22.Gm, 77.84.Fa

Thermodynamics and dielectric properties of the mixed $ Rb_{1 - x} (NH_4)_x H_2 PO_4 $ type compounds

S.I. Sorokov
R.R. Levitsky
A.S. Vdovych

We propose a pseudospin model for proton glasses of the $Rb_{1 - x} (NH_4)_x H_2 PO_4$ type, which takes into account the energy levels of protons around the $PO_4 $ group, a long-range interactions between the hydrogen bonds, and an internal random deformational field. Within the framework of a cluster approximation and a mean field approximation over the long-range interactions, we derive a system of equations for the state parameters and static longitudinal and transverse permittivities. Within the Glauber dynamics approach, we obtain a qualitative description of the temperature behavior of dielectric permittivities of these compounds at different frequencies. We make a survey of experimental and theoretical studies of the properties of proton glass.

Year: 
2007
Pages: 
37
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