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15-06U

15-06U


By Velychko - Posted on 18 December 2015

UDC: 
536.12, 536.71, 536.757
PACS: 
05.70.Ln, 51.30.+i, 44.10.+i

Free energy of the low-density gas in the weakly nonequilibrium heat-conduction steady state

Y.A. Humenyuk

For a low-density gas, the free energy of the weakly nonequilibrium heat-conduction steady state is calculated. Its nonequilibrium part is obtained in the form of a development in gradients of the local temperature up to the 4-th order. The results are analyzed from the viewpoint of the method of thermodynamic potentials of equilibrium thermodynamics. It is shown that the free energy is not consistent with the entropy found out previously, and has not properties of a thermodynamic potential. Reasons and possible ways to overcome this contradiction are discussed.

Year: 
2015
Pages: 
14
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