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02-33U

02-33U


By icmp_admin - Posted on 08 February 2012

UDC: 
536.432.1; 536.44.
PACS: 
05.70.Jk

The thermodynamic characteristics of a binary symmetrical mixture in the vicinity of the vapour-liquid critical point.

M.P. Kozlovskii
O.V. Patsahan
R.S. Melnyk

The implicit expressions for the thermodynamic functions (grand thermodynamic potential, free energy, entropy and heat capacity) of a binary symmetrical mixture in the vicinity of the vapour-liquid critical point are obtained. The collective variables method with a reference system, as well as the procedure of a layer-by-layer integration of a grand partition function are used in our study. For the hard sphere square-well binary mixture the thermodynamic functions (entropy, heat capacity) are calculated as functions of the microscopic parameters of the system.

Year: 
2002
Pages: 
32
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