Condensed Matter Physics, 2014, vol. 17, No. 4, 43703
DOI:10.5488/CMP.17.43703
arXiv:1502.02399
Title:
Electrocaloric effect in KH2PO4 family crystals
Author(s):
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A.S. Vdovych
(Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine)
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A.P. Moina
(Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine)
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R.R. Levitskii
(Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii str, 79011 Lviv, Ukraine)
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I.R. Zachek
(Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine)
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The proton ordering model for the KH2PO4 type ferroelectrics is modified by taking into account the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle cluster approximation we calculate the crystal polarization and explore the electrocaloric effect. Smearing of the ferroelectric phase transition by a longitudinal electric field is described. A good agreement with experiment is obtained.
Key words:
electrocaloric effect, KDP, cluster approximation, polarization
PACS:
77.84.Fa, 77.70.+a
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