Title: Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions
Author(s):

	X.-G. Han (School of Mathematics, Physics and Biological engineering, Inmongolia Science and Technology University, Baotou 014010, China; Key laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inmongolia Science and Technology University, Baotou 014010, China) ,
	Y.-H. Ma (School of Mathematics, Physics and Biological engineering, Inmongolia Science and Technology University, Baotou 014010, China; Key laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inmongolia Science and Technology University, Baotou 014010, China) ,
	S.-L. Ouyang (Key laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inmongolia Science and Technology University, Baotou 014010, China)

The effects of the length of each hydrophobic end block N_st and polymer concentration φ_P on the transition broadness in amphiphilic ABA symmetric triblock copolymer solutions are studied using the self-consistent field lattice model. When the system is cooled, micelles are observed, i.e.,the homogenous solution (unimer)-micelle transition occurs. When N_st is increased, at fixed φ_P, micelles occur at higher temperature, and the temperature-dependent range of micellar aggregation and half-width of specific heat peak for unimer-micelle transition increase monotonously. Compared with associative polymers, it is found that the magnitude of the transition broadness is determined by the ratio of hydrophobic to hydrophilic blocks, instead of chain length. When φ_P is decreased, given a large N_st, the temperature-dependent range of micellar aggregation and half-width of specific heat peak initially decease, and then remain nearly constant. It is shown that the transition broadness is concerned with the changes of the relative magnitudes of the eductions of nonstickers and solvents from micellar cores.

Key words: transition broadness, self-consistent field, amphiphilic copolymer
PACS: 61.25.Hp, 64.75.+g, 82.60.Fa

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