Condensed Matter Physics, 2011, vol. 14, No. 3, 33605: 1-12
DOI:10.5488/CMP.14.33605
arXiv:1202.4548
Title:
Maier-Saupe nematogenic fluid: field theoretical approach
Author(s):
 
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M. Holovko
(Institute for Condensed Matter Physics of the
National Academy of Sciences of Ukraine, 1 Svientsitskii Str.,
79011 Lviv, Ukraine),
 
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D. di Caprio
(Laboratoire d'Electrochimie, Chimie des Interfaces
et Modélisation pour l'Energie (LECIME) ENSCP, Chimie
ParisTech, Case 39, 4 Pl. Jussieu, 75005 Paris, France),
 
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I. Kravtsiv
(Institute for Condensed Matter Physics of the
National Academy of Sciences of Ukraine, 1 Svientsitskii Str.,
79011 Lviv, Ukraine)
| | |
We adopt a field theoretical approach to study the structure
and thermodynamics of a homogeneous Maier-Saupe nematogenic
fluid interacting with anisotropic Yukawa potential. In the
mean field approximation we retrieve the standard Maier-Saupe
theory for liquid crystals. In this theory the density is
expressed via the second order Legendre polynomial of molecule
orientations. In the Gaussian approximation we obtain
analytical expressions for the correlation functions, the
elasticity constant, the free energy, the pressure, and the
chemical potential. We also use Ward symmetry identities to set
a simple condition for the correlation functions. Subsequently
we find corrections due to fluctuations and show that density
now contains Legendre polynomials of higher orders.
Key words:
Maier-Saupe nematogenic fluid, field theoretical
approach, correlation function, thermodynamics
PACS:
64.70.M-, 64.10.+h, 05.70.Fh
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