Condensed Matter Physics, 2010, vol. 13, No. 2, p. 23602:1-15
DOI:10.5488/CMP.13.23602
Title: Statistical field theory for liquid vapor interface
Author(s):
 
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V. Russier
(ICMPE, UMR 7182 CNRS and Université Paris Est 2-8 rue Henri
Dunant, 94320 Thiais, France)
,
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J.-M. Caillol
(Laboratoire de Physique Théorique, UMR 8627 CNRS and Université
de Paris Sud, bat. 210, 91405 Orsay Cedex, France) |
A statistical field theory for an inhomogeneous
liquid, a planar liquid/vapor interface, is devised from first
principles. The grand canonical partition function is represented
via a Hubbard-Stratonovitch transformation leading, close to
the critical point, to the usual φ4 scalar field theory
which is then rigorously considered at the one-loop level. When
further simplified it yields the well-known capillary wave theory
without any ad hoc phenomenological parameter. Internal
coherence of the one-loop approximation is discussed and good
overall qualitative agreement with recent numerical simulations is
stressed.
Key words: field theory, gas-liquid interface, surface
tension
PACS: 61.30.Hn, 64.70.F, 68.03.Cd
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