Title:
The contact theorem and sum rules in the theory of electrical
double layer
Authors:
M.F.Holovko
(Institute for Condensed Matter Physics of the
National Academy of Sciences of Ukraine, 1 Svientsitskii Str.,
79011 Lviv, Ukraine),
J.P.Badiali
Laboratoire de Electrochimie
et Chimie Analytique ENSCP-UPMC, 11 rue P. et M. Curie, 75231
Cedex 05, Paris,
France)
The specific sum rules in the theory of electrical double layer are formulated as the consequence of contact theorem. They concern the correlation functions of electrolyte when one ion is located on the surface. A simple interpretation of the obtained relations is given.
Key words:
electrolyte solution, double layer, contact theorem, sum
rules
PACS:
05.20.Jj, 05.30.Fk, 05.10.Zn
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