Title:
THE PHASE TRANSITIONS CHARACTER AND MICROSCOPIC MODELS FOR
Sn_2P_2S(Se)_6 FERROELECTRICS
Author(s):
Yu.Vysochanskii, A.Drobnich (Institute for Solid State Physics and Chemistry,
Uzhgorod National University, 46 Pidgirna Str., 88000 Uzhgorod, Ukraine)
The paper considers an example of concrete objects, i.e. ferroelectrics of Sn$_2$P$_2$S$_6$ family, for which, according to general estimations, a correlation between the shape of a phase diagram (the presence of a Lifshitz point and of a tricritical point) and a crossover ``displacive to order/disorder'' is observed. Simulations by means of microscopic models, which most adequately represent a dipole ordering in these crystals, are analyzed. A dimension dependence of a ferroelectric phase transition temperature for microcrystals of Sn$_2$P$_2$S$_{6}$ compound is considered.
Key words:
ferroelectrics, displacive vs. order/disorder crossover,
Lifshitz point, incommensurate phase, microscopic models, Monte
Carlo simulations
PACS:
64.60.Cn
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