Condensed Matter Physics, 2022, vol. 25, No. 1, 13502
DOI:10.5488/CMP.25.13502
arXiv:2203.14107
Title:
Non-extensive thermodynamics of the radiation in heterogeneous thermal plasmas
Author(s):
 
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G. S. Dragan
(Physics Research Institute, Odesa I. I. Mechnikov National University, Dvorianska, 2, Odesa, Ukraine, 65082),
 
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V. V. Kutarov
(Physics Research Institute, Odesa I. I. Mechnikov National University, Dvorianska, 2, Odesa, Ukraine, 65082),
 
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A. Y. Bekshaev
(Physics Research Institute, Odesa I. I. Mechnikov National University, Dvorianska, 2, Odesa, Ukraine, 65082)
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Thermodynamic characteristics of the radiation of condensed combustion products presented in the form of agglomerates of metal-oxide
nanoparticles demonstrate deviations from the classical Planck’s law. We propose to interpret these deviations in terms of the non-additive
entropy of the photon system interacting with the heterogeneous combustion products, which makes it possible to use the non-extensive Tsallis
thermodynamics for their description. It is assumed that the non-additive character of the radiation entropy in heterogeneous plasma can be
explained by the influence of long-range interactions and non-equilibrium physicochemical processes. An expression is obtained for the
energy-dependent distribution of the photon density, based on the phenomenological parameter of non-extensiveness q which, in the
first approximation, does not depend on the energy. In this case, the "non-extensive" Planck’s law can be reduced to the "usual"
Planck distribution by introducing the "effective temperature" that exceeds the real temperature. Numerical modelling has shown that
the spectral density of photons, the position and magnitude of its maximum depend on the value of the parameter q, which can be
used for its experimental determination and revelation of its physical nature and origin.
Key words:
entropy, radiation, heterogeneous plasma, Tsallis thermodynamics
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