Condensed Matter Physics, 2012, vol. 15, No. 3, p. 33603:1-17
DOI:10.5488/CMP.15.33603
arXiv:1207.2881
Title:
Disorder effects on the static scattering function of star branched polymers
Author(s):
 
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V. Blavatska
(Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 79011 Lviv, Ukraine)
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C. von Ferber
(Applied Mathematics Research Centre, Coventry University, CV1 5FB Coventry, UK; Institut für Theoretische Physik II, Heinrich-Heine Universität Düsseldorf, D–40225 Düsseldorf, Germany)
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Yu. Holovatch
(Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 79011 Lviv, Ukraine)
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We present an analysis of the impact of structural disorder on the static scattering function of f-armed star branched polymers in d dimensions. To this end, we consider the model of a star polymer immersed in a good solvent in the presence of structural defects, correlated at large distances r according to a power law ~r-a. In particular, we are interested in the ratio g(f) of the radii of gyration of star and linear polymers of the same molecular weight, which is a universal experimentally measurable quantity. We apply a direct polymer renormalization approach and evaluate the results within the double ϵ = 4 - d, δ = 4 - a-expansion. We find an increase of g(f) with an increasing δ. Therefore, an increase of disorder correlations leads to an increase of the size measure of a star relative to linear polymers of the same molecular weight.
Key words:
polymers, structural disorder, universality, renormalization group
PACS:
61.41.+e, 61.25.hp, 64.60.ae
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